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Oxygen Reduction Catalyst for Active Corrosion Protection of Epoxy Coating

Received: 26 October 2021    Accepted: 16 November 2021    Published: 17 November 2021
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Abstract

Metal corrosion has spread all over all aspects of national economy and life, causing serious economic losses and ecological hazards. Because of its excellent protective effect and universality, coating has become an important choice for metal corrosion protection. Although the conventional coating can realize metal corrosion protection with its shielding effect, the protection performance gradually decreases due to mechanical damage and corrosive species erosion. Based on the actual corrosion reaction process, the concept of nanocatalytic anticorrosion is proposed in this work to realize the long-term protection for metals. Firstly, oxygen reduction catalyst was obtained by confined pyrolysis and added into epoxy resin to prepare a new nanocatalytic anticorrosion coating, and then the protective performance of the coating was studied in detail. The results show that the catalyst adopt a uniform dodecahedral structure with excellent oxygen reduction ability, the half wave potential is 0.85 V. The catalyst added in the coating can spontaneously consume the diffused oxygen in the coating while enhancing the compactness of the coating to block the corrosive medium, reduceing the contribution of the corrosive medium to the corrosion reaction. Therefore, the probability of metal corrosion can be significantly reduced, and the service life of the coating for metal protection has been greatly prolonged.

Published in Science Discovery (Volume 9, Issue 6)
DOI 10.11648/j.sd.20210906.25
Page(s) 366-370
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Confined Pyrolysis, Oxygen Reduction Reaction, Nanocatalytic Anticorrosion, Smart Coating

References
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[5] Wang, D.; Yang, X.; Yu, H.; Gu, J.; Qi, D.; Yao, J.; Ni, Q.Smart Nonwoven Fabric with Reversibly Dual-Stimuli Responsive Wettability for Intelligent Oil-Water Separation and Pollutants Removal [J]. J. Hazard. Mater. 2020, 383, 121123.
[6] Das, B. P.; Tsianou, M. From Polyelectrolyte Complexes to Polyelectrolyte Multilayers: Electrostatic Assembly, Nanostructure, Dynamics, and Functional Properties [J]. Adv. Colloid Interface Sci. 2017, 244, 71-89.
[7] Débora Abrantes Leal, Fernando Wypych, and Cláudia Eliana Bruno Marino. Zinc-Layered Hydroxide Salt Intercalated with Molybdate Anions as a New Smart Nanocontainer for Active Corrosion Protection of Carbon Steel [J]. ACS Appl. Mater. Interfaces 2020, 12, 17, 19823–19833.
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[10] Ting Wang, LingHua Tan, ChenDi Ding, MingDong Wang, JianHua Xua and Jia Jun Fu. Redox-triggered controlled release systems-based bi-layered nanocomposite coating with synergistic self-healing property [J]. J. Mater. Chem. A, 2017, 5, 1756.
[11] Shichao Ding, Zhaoyuan Lyu, Hong Zhong, Dong Liu, Erik Sarnello, Lingzhe Fang, Mingjie Xu, Mark H. Engelhard, Hangyu Tian, Tao Li, Xiaoqing Pan, Scott P. Beckman, Shuo Feng, Dan Du, Jin-Cheng Li, Minhua Shao, Yuehe Lin. An Ion-Imprinting Derived Strategy to Synthesize Single-Atom Iron Electrocatalysts for Oxygen Reduction [J]. Small 2020, 2004454.
[12] Cheng Zhu, Yijun Fu, Changan Liu, Y ang Liu, Lulu Hu, Juan Liu, Igor Bello, Hao Li, Naiyun Liu, Sijie Guo, Hui Huang, Yeshayahu Lifshitz, Shuit-T ong Lee,and Zhenhui Kang. Carbon Dots as Fillers Inducing Healing/Self-Healing and Anticorrosion Properties in Polymers [J]. Adv. Mater. 2017, 1701399.
[13] Sepideh Pourhashem, Mohammad Reza Vaezi, Alimorad Rashidi, Mohammad Reza Bagherzadeh, Exploring corrosion protection properties of solvent based epoxy-graphene oxide nanocomposite coatings on mild steel [J]. Corrosion Science, Volume 115, 2017, 78-92.
[14] 孙志华,蔡建平,刘明,陆峰,陶春虎.金属/有机涂层体系环境失效的电化学研究方法[J].装备环境工程,2007(04):1-5。
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Cite This Article
  • APA Style

    Meng Cheng, Junhao Liu, Shuangqing Sun, Songqing Hu. (2021). Oxygen Reduction Catalyst for Active Corrosion Protection of Epoxy Coating. Science Discovery, 9(6), 366-370. https://doi.org/10.11648/j.sd.20210906.25

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    ACS Style

    Meng Cheng; Junhao Liu; Shuangqing Sun; Songqing Hu. Oxygen Reduction Catalyst for Active Corrosion Protection of Epoxy Coating. Sci. Discov. 2021, 9(6), 366-370. doi: 10.11648/j.sd.20210906.25

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    AMA Style

    Meng Cheng, Junhao Liu, Shuangqing Sun, Songqing Hu. Oxygen Reduction Catalyst for Active Corrosion Protection of Epoxy Coating. Sci Discov. 2021;9(6):366-370. doi: 10.11648/j.sd.20210906.25

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  • @article{10.11648/j.sd.20210906.25,
      author = {Meng Cheng and Junhao Liu and Shuangqing Sun and Songqing Hu},
      title = {Oxygen Reduction Catalyst for Active Corrosion Protection of Epoxy Coating},
      journal = {Science Discovery},
      volume = {9},
      number = {6},
      pages = {366-370},
      doi = {10.11648/j.sd.20210906.25},
      url = {https://doi.org/10.11648/j.sd.20210906.25},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20210906.25},
      abstract = {Metal corrosion has spread all over all aspects of national economy and life, causing serious economic losses and ecological hazards. Because of its excellent protective effect and universality, coating has become an important choice for metal corrosion protection. Although the conventional coating can realize metal corrosion protection with its shielding effect, the protection performance gradually decreases due to mechanical damage and corrosive species erosion. Based on the actual corrosion reaction process, the concept of nanocatalytic anticorrosion is proposed in this work to realize the long-term protection for metals. Firstly, oxygen reduction catalyst was obtained by confined pyrolysis and added into epoxy resin to prepare a new nanocatalytic anticorrosion coating, and then the protective performance of the coating was studied in detail. The results show that the catalyst adopt a uniform dodecahedral structure with excellent oxygen reduction ability, the half wave potential is 0.85 V. The catalyst added in the coating can spontaneously consume the diffused oxygen in the coating while enhancing the compactness of the coating to block the corrosive medium, reduceing the contribution of the corrosive medium to the corrosion reaction. Therefore, the probability of metal corrosion can be significantly reduced, and the service life of the coating for metal protection has been greatly prolonged.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Oxygen Reduction Catalyst for Active Corrosion Protection of Epoxy Coating
    AU  - Meng Cheng
    AU  - Junhao Liu
    AU  - Shuangqing Sun
    AU  - Songqing Hu
    Y1  - 2021/11/17
    PY  - 2021
    N1  - https://doi.org/10.11648/j.sd.20210906.25
    DO  - 10.11648/j.sd.20210906.25
    T2  - Science Discovery
    JF  - Science Discovery
    JO  - Science Discovery
    SP  - 366
    EP  - 370
    PB  - Science Publishing Group
    SN  - 2331-0650
    UR  - https://doi.org/10.11648/j.sd.20210906.25
    AB  - Metal corrosion has spread all over all aspects of national economy and life, causing serious economic losses and ecological hazards. Because of its excellent protective effect and universality, coating has become an important choice for metal corrosion protection. Although the conventional coating can realize metal corrosion protection with its shielding effect, the protection performance gradually decreases due to mechanical damage and corrosive species erosion. Based on the actual corrosion reaction process, the concept of nanocatalytic anticorrosion is proposed in this work to realize the long-term protection for metals. Firstly, oxygen reduction catalyst was obtained by confined pyrolysis and added into epoxy resin to prepare a new nanocatalytic anticorrosion coating, and then the protective performance of the coating was studied in detail. The results show that the catalyst adopt a uniform dodecahedral structure with excellent oxygen reduction ability, the half wave potential is 0.85 V. The catalyst added in the coating can spontaneously consume the diffused oxygen in the coating while enhancing the compactness of the coating to block the corrosive medium, reduceing the contribution of the corrosive medium to the corrosion reaction. Therefore, the probability of metal corrosion can be significantly reduced, and the service life of the coating for metal protection has been greatly prolonged.
    VL  - 9
    IS  - 6
    ER  - 

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Author Information
  • School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, China

  • School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, China

  • School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, China

  • School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, China

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